There is some company out there that makes a gun holster that clips onto the top of the shaft of the boot.
The main problem with this, is:
1. The gun resides on the inside of the boot. So you need really skinny calves.
2. You need to be able to pull your pant leg up higher than the top of the boot to access it. You are talking about pulling your pant leg up 12 or more inches. Not practical.
Most holsters deny you access when seated, especially if you are belted in while in your car. So an ankle holster is good for that scenario.